Hyperlink Control for mailto: to be used like this anywhere in the page
<asp:HyperLink ID="HyperLink1" runat="server" Text='<%# Eval("EMail") %>'
NavigateUrl='<%# Eval("EMail", "mailto:{0}") %>'></asp:HyperLink>
HyperLinks in the GridView Row link use as Mailto:<asp:TemplateField HeaderText="EMail" SortExpression="EMail"> <ItemTemplate>
<asp:HyperLink ID="HyperLink1" runat="server" NavigateUrl='<%# Eval("EMail", "mailto:{0}") %>'
Text='<%# Eval("EMail") %>'></asp:HyperLink>
</ItemTemplate> </asp:TemplateField>